ISO 17075 PDF

Nov 15, ISO (E). IULTCS/IUC (E). PDF disclaimer. This PDF file may contain embedded typefaces. In accordance with Adobe’s. Feb 28, An updated version of BS EN ISO , the internationally recognised method for the analysis of chrome VI in leather, is due to be published. The international test method to determine the chromium VI content in leathers is EN ISO This method has a limit of detection of 3mg/kg, which is the.

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Allergic reactions to chromium VI can often be severe, leading to ixo complications with the skin. In the context of EN ISOthis means the liquid extraction solution travels around the sorbent particles and the dye molecules are removed from the liquid, and adsorbed onto the surface of the sorbent.

To receive the Monthly Technical Update email, you simply need to complete this form. Chromium sulphate salts are commonly used as tanning agents for leathers articles used in footwear uppers, handbags, belts and upholstery.

This is a very important parameter for tanneries, brand owners and retailers — both from a general product safety perspective and in terms of legal compliance. Another less commonly known use for chromium is as the green pigment within tattoo inks.

The leather is cut into small pieces and placed in a phosphate buffer at pH 7.

Step 2 Tell us about your business. This reaction could theoretically occur during leather processing after tanning, during storage or after the product reached the consumer, although as chromium-tanned leather is an acidic material, the likelihood of conversion to chromium VI in finished leather is reduced. Where did you first hear about Eurofins BLC?

According to a scientific study carried out in Germany, the number of people hypersensitive to chromium VI is low.

ISO – Leather — Chemical tests — Determination of chromium(VI) content

These precipitates would, in effect, remove the chromium VI from the water-based solution and give an artificially low final result. The sorbent in these cartridges consists of very small, solid particles, that adsorb the dye molecules onto the surfaces of the particles, physically adhering ions and molecules onto the surface of another phase.


This website uses cookies. From successful trials to commercial implementation; this DNA tagging system is one of the most accurate forms of These salts contain chromium in its trivalent state chromium III.

Chromium VI test method updated

The colour intensity of the solution ieo 1,5-diphenylcarbazone has a direct relationship to the amount of chromium VI present in the solution. Preparing specimens for HPLC analysis. For individual concerns about products, please contact 177075 manufacturer. Colour fastness to artificial light: These dyes can interfere with the detection technique UV-Visible spectrophotometerso a clean-up stage follows where the solution is passed through cartridges to remove the colour from the extract.

However, the chemical reaction from chromium III to chromium VI — Cr VI — is an oxidation process and can be facilitated by certain factors — for example, increases in pH, temperature, exposure to ultraviolet UV radiation and exposure to oxidising agents.

Tell us how we can contact you. As REACH Annex XVII entry 47 restricts chromium VI in leather articles and articles containing leather due to chromium allergic dermatitis and other health concerns, everyone involved in the supply chain has a responsibility to ensure that chromium VI is not present in their products. Step 3 Tell us how we can contact you. Testing for chromium VI by the colourimetric method. Contact Eurofins BLC to discuss your enquiry with friendly and helpful experts and to get a quotation.

If you are a SATRA member but not yet registered for online access please register as a new user below. Step 1 Tell us about your enquiry. This means that for leather bearing in mind that chromium-tanned leather will normally be acidic due to the processes involved in the tanning processthe pH of the extraction solution will generally remain between 7.

It is this chromatography that reduces the possible interferences compared with the UV-Vis detection technique. In the test method, the pH of this extraction solution is crucial in order to avoid artificially promoting the conversion of chromium III to chromium VI, or instigating the formation of chromium VI precipitates.


Under well-managed production conditions, chromium-tanned leather should pose a very low risk of containing chromium VI.

Trivalent chromium is a vital trace element within the human diet — specifically for the insulin hormone which requires chromium to work properly.

Chromium VI is a dermatological irritant, and exposure to a small amount of it can trigger an immune response, causing sensitisation of the skin. Ion chromatography is the separation and quantitative analysis of anions and cations in an ionic solution using the ion exchange method of liquid chromatography. The leather is cut in to small pieces and placed in a phosphate buffer at pH 7. End of Year Leather Suppliers, manufacturers, brands and retailers need to be aware of this new POPs regulation and the chemical compliance The extraction solution is referred to as a ‘buffer’ solution, because it resists a change in pH when small quantities of acid or alkali are added.

As a result, the mixture is separated into substances which appear as separate peaks on the HPLC chromatogram.

How can we help? By continuing to sio this site, you agree to our use of cookies. The most dangerous hazard associated with chromium VI is its carcinogenicity the ability to cause cancer. Due to the way leather is processed in batches with each animal skin being slightly different and the complex chemistry involved with chromium VI formation, testing is the only certain way of demonstrating compliance.

Chromium VI test method updated

Tell us about your business. We will be keeping an eye on this at BLC and will keep our members informed. Ido intensity of this colour is measured using an ultraviolet visible light spectrophotometer UV-Viswhich measures the absorbance of 1,5-diphenylcarbazone at a wavelength of nm.

The method states that if a leather sample is tested to both and and there is a difference in the results, the result from ion chromatography should be considered as the reference. These ageing methods are designed to assess the propensity for chrome VI to form in leather.